Would you have your data file on the NAS? or on the server? Keep it on the server, get 15K SAS drives or SSD's in the server - even if small ones dedicated to running QB - and it will probably matter little how you access it, but accessing it by users remoting into the server would eliminate the network overhead for QB - using a data file of that size, you don't want to make it harder for QB than necessary. Just my opinion.
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